Second Law of Thermodynamics Calculator
Calculate entropy change, thermal efficiency, and reversible/irreversible process parameters. Step-by-step solutions for engines, refrigerators, and turbines.

second law of thermodynamics calculator:
Use this Second Law of Thermodynamics Calculator to determine entropy change, thermal efficiency, and lost work in reversible or irreversible processes. Enter heat, work, and temperatures to compute ΔS, η, and COP with step-by-step solutions.
second law of thermodynamics Tool Formula:
Entropy Change (ΔS):
\[ \Delta S = \frac{Q}{T} \]
Heat Engine Efficiency (η):
\[ \eta = 1-\frac{Tc}{Th} \]
The Second Law of Thermodynamics Calculator helps engineers, students, and researchers analyze energy transfer limitations and entropy changes in thermodynamic systems. The second law states that entropy of an isolated system always increases in irreversible processes, and no heat engine can be 100% efficient.
Users can input heat transfer (Q), temperatures (T_H, T_C), work done (W), and process details. The calculator computes entropy change (ΔS), thermal efficiency (η), coefficient of performance (COP) for refrigerators/heat pumps, and quantifies irreversibility or lost work. Step-by-step solutions illustrate formulas for reversible, irreversible, and real thermodynamic cycles, making it easy to analyze engines, turbines, compressors, and refrigerators.
SI units are supported: J, kJ, K, Pa, m³, °C. This tool is ideal for mechanical engineers, chemical engineers, thermal engineers, and students, ensuring accurate entropy analysis and energy efficiency evaluation in practical and ideal systems.
⚡ Work & Installation Input to Output:
Input:
- Heat transferred (Q_H, Q_C)
- Hot and cold reservoir temperatures (T_H, T_C)
- Work done (W)
- Optional: process type (reversible, irreversible)
- Units: J, kJ, Pa, m³, K, °C
Processing:
- Compute entropy change: ΔS = Q_rev / T for reversible processes
- Compute thermal efficiency: η = 1 – T_C / T_H for Carnot engines
- Compute coefficient of performance (COP) for refrigerators/heat pumps
- Determine irreversibility: I = T_0 ΔS_gen, where ΔS_gen is entropy generated
- Validate input values and units
Output:
- Entropy change (ΔS)
- Thermal efficiency (η)
- Coefficient of performance (COP)
- Irreversibility or lost work
- Step-by-step formulas and calculations
Testing and Final Adjustments
Test common scenarios:
- Carnot engine: T_H = 600 K, T_C = 300 K → η = 50%
- Reversible process: Q_H = 500 kJ, T_H = 500 K → ΔS = 1 kJ/K
- Refrigerator: Q_C = 200 kJ, T_C = 270 K, T_H = 300 K → COP calculation
- Edge cases: very high/low temperatures, Q = 0, W = 0, fully irreversible processes
- Units validation: J ↔ kJ, °C ↔ K, Pa ↔ kPa
- Step-by-step clarity for students and engineers
- Mobile/desktop UX: numeric keypad, labels, dropdown for process selection
- Include examples: steam turbine, internal combustion engine, heat pump
- SEO metadata: "Second Law of Thermodynamics Calculator," "Entropy Calculator," "Thermal Efficiency Tool," schema markup
Frequently Asked Questions - Second Law of Thermodynamics Calculator:
What is the second law of thermodynamics?
It states that entropy of an isolated system always increases in irreversible processes, and no heat engine can be 100% efficient.
How do I calculate entropy change?
For a reversible process, ΔS = Q_rev / T, where Q_rev is heat transferred reversibly and T is temperature.
How do I calculate thermal efficiency?
For Carnot engine, η = 1 – T_C / T_H, where T_H and T_C are hot and cold reservoir temperatures.
What is irreversibility?
Irreversibility or lost work is the energy that cannot be converted to work due to entropy generation.
What is COP?
Coefficient of performance (COP) measures the efficiency of a refrigerator or heat pump: COP = Q_C / W.
Which units are supported?
Energy in J or kJ, temperature in K or °C, pressure in Pa, volume in m³.
Who should use this calculator?
Mechanical, chemical, and thermal engineers, as well as students analyzing entropy and efficiency.
Can it handle reversible and irreversible processes?
Yes, the calculator supports both reversible and irreversible process analysis.
Does it show step-by-step calculations?
Yes, all formulas and intermediate steps are displayed for clarity.
Why is it important?
It ensures accurate energy and entropy analysis for engines, turbines, compressors, and refrigeration systems.
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